þ7#,á:]$ÜfÜfÜfÜfÜfÜtJÝXÝXÝXÝdÝtÝŠÝŠÝ¤xÜ¾šÞ Þ<ß*ß-ÛÜfßÞT¯ßßá2ßßßßßßNAME _________________ CHEMISTRY 141 First Hour Exam, September 28, 1994 Constants: To = 273.2 K NA = 6.023 x 1023 mol-1 You must answer all questions. Please circle your final answer to each problem. For full credit you must show all work. We will give partial credit for work; however, we will not hunt for what you did. 1. (3 points) What is the element with 16 protons and 18 neutrons? _____________________ 2. (3 points) What is the neutral element having 12 electrons and 12 neutrons? ___________ 3. (5 points) The following isotopes of chlorine and their abundances are known. What is the elemental molar mass of chlorine? 37Dba12()17Cl 25% , 35Dba12()17Cl 75% 4. (5 points) We have done a couple of things with pennies this semester. If we know the density of copper to be 8.92 g/mL, and the mass of a penny to be 2.50g, how much water will 10 pennies displace if they are placed carefully in a graduated cylinder? 5. (6 points) You have 0.028 g of magnesium metal (Mg). How many atoms do you have? 6. (7 points) What is the most likely charge associated with the ions formed from these elements? Br ____________________________ Na ____________________________ Ca ____________________________ Ag ____________________________ Al ____________________________ Zn ____________________________ O ____________________________ 7. (9 points) Provide formulas for ionic compounds made from the following ions: 8. (5 points) Name the following binary compounds. SO2 __________________________________________ P2S5 __________________________________________ MgO __________________________________________ LiH __________________________________________ HCl __________________________________________ 9. (9 points) Use one of the following two structures to answer this problem. Be sure to let us know which calculation you are doing by circling the structure of the compound you use. a) Give the molecular formula. b) What is the molecular molar mass? c) Given 5.0x10-3 grams of compound, how many molecules will there be? I. Testosterone: All men have testosterone as a major sex hormone. II. Estrone: Women have a unique sex hormone, the only aromatic hormone of the human sex hormones. 10. (9 points) A compound containing carbon, sulfur, and hydrogen is combusted completely with excess oxygen to produce 2.766 g of SO2, 1.900 g of CO2, and 1.168 g of H2O. What is the empirical formula of the compound? 10 cont. If the molar mass of the compound is determined to be 798 g by mass spectral analysis, what is the molecular formula? 11. (10 points) Galactose is a common sugar very similar to glucose and is found in milk. If you do not have the correct enzyme ( a genetic disorder easily tested for in infants) to convert galactose to glucose you have to have restricted milk intake as a baby, or serious brain damage may result. You have 12.5 grams of galactose (C6H12O6) in 5.0 liters of solution. a) What is the molarity of your sugar solution? b) If you drink 250. mL of the solution how many grams of galactose will you have ingested? 12. (10 points) If you have 32. grams of sodium carbonate in a total volume of 250. mL, what is the molarity of the sodium in the solution? 13. (9 points) Outline the procedure in detail for making 2.0 liters of a 1.00 M HNO3 solution from a concentrated stock solution of 70.4% (w/w) HNO3 (d = 1.423 g/ml). 14. (10 points) Balance the following reaction for the combustion of benzene. 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cp f 7180 1270 M 7180 1430 l 7340 1430 l 7340 1270 l cp f gr np 7300 3470 M 7220 3470 l 7220 870 l 7300 870 l cp f gr count origstk sub{P}rp end chemsave restore ¿ Œ,Times .ÿÿ+f`Mercury(II) Œ+$ Iron(III) Œ(©iCu(I) Œ(7« Phosphate Œ+wNitrate Œ+hPerchlorate ¡dªCHMDSTRGV³È x(XP6ÿÿÿÿÿÿPP#P ˜¼x¼pT€¼40#P ð0 È#( ˜ ˜#( ˜Tp\ ˜\ÿÿÿÿ ÿÿÿÿÿÿÿÿ€øàø¼XMercury(II) € PH °H xT Iron(III)€ 44”4 \ (Cu(I) L \ ¬ \ˆ Phosphateh`¨ À¨`(NitrateˆÈèÈˆ"ìPerchlorateTimesÿÿÿÿÿÿÿÿÿÿÿÿÿÿÿÿÿÿÿ2 ‰Ù2‰Ù2g™@ÿÿÿÿÿg@™¡òCHMDg™@Gr‰ph¯bj¡dCHMDUntitled Document-4¡d†CHMDÐÐ€þÈþÔ¸¼g(üÐÐ€d'@ÐÐÐÐ Ä¡Àcount ¿ ef g™@ Ä¡Àcurrentpoint 192837465 ¿!g Ä¡À currentpoint ¿ g™@"g Ä¡Àsave/chemsave exch def ¡Àé%%BeginProcSet: chemdict30 24 10 % ChemDraw Laser Prep % Copyright 1986-1993, Cambridge Scientific Computing, Inc. userdict/chemdict30 210 dict put chemdict30 begin/version 24 def/sv 10 def/b{bind def}bind def/L{load def}b/R{null def}b/d/def L/a/add L/al/aload L/as/astore L/at/atan L/cp/closepath L/cv/curveto L/cw/currentlinewidth 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"d…ñ"‘Ôæñ"‚íç"eí"UÔ"UÓç"Uç"8"(î"7Óñ"UÓâ"^$ä÷"F5ï".$".$ä Œ"ró"pó "M¹" ".$ë¡Ànend %%EndProcSet 40 80 20 20 54 chemdict30 begin/hS x/sf x/lW x/bW x/cW x/sh T d 217 137 103 16 SPn/origstk x 65535 65535 65535 sBg 0 0 0 C np 2680 2604 M 2660 2616 l 2660 2004 l 2680 2016 l cp f np 3190 2898 M 3190 2922 l 2660 2616 l 2680 2604 l cp f np 3700 2604 M 3710 2610 l 3710 2622 l 3190 2922 l 3190 2898 l cp f np 3633 2559 M 3643 2577 l 3195 2836 l 3185 2818 l cp f np 3700 2016 M 3710 2010 l 3720 2016 l 3720 2604 l 3710 2610 l 3700 2604 l cp f np 3190 1722 M 3190 1698 l 3700 1992 l 3710 2010 l 3700 2016 l cp f np 3190 1698 M 3190 1722 l 2680 2016 l 2660 2004 l cp f np 4230 2898 M 4230 2922 l 3710 2622 l 3710 2610 l 3720 2604 l cp f np 4740 2604 M 4760 2616 l 4230 2922 l 4230 2898 l cp f np 4740 2016 M 4750 2010 l 4760 2016 l 4760 2616 l 4740 2604 l cp f np 4230 1722 M 4230 1710 l 4240 1704 l 4750 1998 l 4750 2010 l 4740 2016 l cp f np 4220 1704 M 4230 1710 l 4230 1722 l 3720 2016 l 3710 2010 l 3720 1992 l cp f np 5260 1704 M 5270 1710 l 5271 1721 l 4760 2016 l 4750 2010 l 4750 1998 l cp f np 5260 1116 M 5270 1110 l 5280 1118 l 5280 1702 l 5270 1710 l 5260 1704 l cp f np 4750 822 M 4750 798 l 5260 1092 l 5270 1110 l 5260 1116 l cp f np 4240 1116 M 4220 1104 l 4750 798 l 4750 822 l cp f np 4220 1104 M 4240 1116 l 4240 1704 l 4230 1710 l 4220 1704 l cp f np 5837 1883 M 5845 1907 l 5271 1721 l 5270 1710 l 5280 1702 l cp f np 6181 1409 M 6205 1409 l 5845 1907 l 5837 1883 l cp f np 5837 936 M 5841 924 l 5853 924 l 6205 1409 l 6181 1409 l cp f np 5834 915 M 5841 924 l 5837 936 l 5280 1118 l 5270 1110 l 5280 1096 l cp f np 2297 2903 M 2287 2887 l 2699 2621 l 2709 2637 l cp f np 2259 2843 M 2249 2827 l 2665 2560 l 2675 2576 l cp f np 3700 1540 M 3720 1540 l 3720 1992 l 3710 2010 l 3700 1992 l cp f np 5260 640 M 5280 640 l 5280 1096 l 5270 1110 l 5260 1092 l cp f np 6073 502 M 6091 512 l 5853 924 l 5841 924 l 5834 915 l cp f gr count origstk sub{P}rp end chemsave restore ¿ Œ, Helvetica .ÿÿ+h—O Œ(K¶CH ñ€+3 Œ (CH ñ€+3 Œ (/OH Œ,Times (–ùTestosterone ¡dôCHMDSTRGg™@ x(XP6ÿÿÿÿÿÿä x < xh€ <ˆäˆ¸€h <˜ ä˜¸¸ ` 4˜`qÛ‹;¦Û €JŒˆL NŸPÿÿÿÿ !"#$KMOQÿÿÿÿÿÿOCH3CH3OHÿÿÿî`Á Ð%R@4ÌÀÿí`þ Ü8SPL ÿì` XPTÌd€¸ÿë`X ïUhÀôØn¸tVt¸$Testosterone HelveticaTimesÿÿÿÿÿÿÿÿÿÿÿÿÿÿÿÿÿÿÿ2”Ù1ø”Ù1èÜfp?ÿÿÿÿÿfÜ?p¡òCHMDÜfp?Gr‰ph¯bj¡dCHMDUntitled Document-4¡d†CHMDÐÐ€þÈþÔ¸¼g(üÐÐ€d'@ÐÐÐÐ Ä¡Àcount ¿ ÚdÛe Üfp? 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A tablet contains 120. mg of verapamil. How many moles of nitrogen are in one tablet ¡tv‚‚µƒƒŒƒ³)‡n„€‡ˆn¡ai„eƒöƒ ƒ F‡E…³¬‚Pdr…nuoheˆƒ¨zi†ƒ³]JUVWXbcdertxz{}INX¨´ƒ…‡Žœž §©²¸Å¸¹º½ÀÊ#jt¹º»¿Éó $%&RXƒ‰´ºåêôúþôö r s túôóóïëóïëëúóúôúôúôúåóßåóßúôúØóúôúôúôúÑúôúËúËúËúËúËúËúôúÅú¿ú¸@lÌ € ü@;œ@, ô €ü€ € H t v Û Ü Ý ß ã í e f u v ˆ ‰O\žŸ ¢£¤ Y d è ò9:z{™¤äåæçìíóôúûýÐòÐõÐöÐ÷ÐøÐùÑÑÑÑÑ ÑÑÑ ÑÑÑÑÑSÑiÑ¨Ñ©ÑªÑ«ÑÑ®úóúíúçúçúçúíúçúçúçúíúíúáúçúíúçúçúçúçúçúúÛúÕúúáúáúáúáúúúúúúúúú @ @ ü ü €@žì F&JK{}J¤‚ƒ³´µ¸º»¼½y›½ß#Eg¹»¼ï!S„µæùòòòììØÏ¼¨¢œœœœ—‘€€€€€€€pppppppppjppppppp$—$þàð´ð€$þàhð´ð€$K$$à$h$ÿpü,hðð€@$þHhð´ð€$hð$°ýœhð°ð€$h$h$h)æç¡Àå , r s u v Ü Þ ß ¼ ½ ¾ ¿ À Á Â Ã Ä Å ÆFGHIJKÁñòóôõ Q R S T U áðàððÐËÆÁÆ¼·§Ÿ——————————ðððððððððððððððn$þàÿphàP"P ÿ$=þàð´ð€$hþH$hþH ÿ$%hþH$þàð´ð€$”$$‰$$$þàð´ð€$þàð´ð€$þàð´ð€) á â ã äŽ‘’“”ãýÐöÑ©ÑªÑ«Ñ¬ÑÑ®ïïïÞïïïïïïÎ½´¯¯½¯ŸŸïïï¯$þàð´ð€ô$!À$@$ þàÿpàP"P$þàÿpàP"P$þàÿphàP"P$þàÿphàP"Pÿÿÿÿÿÿÿÿÿÿÿÿÿÿÿÿÿÿÿÿÿÿÿÿÿ ÿÿÿÿÿÿÿÿÿÿÿÿÿÿóôöÞ‚@}L ¦ D‚ÿÿcÿÿGÿÿvÿÿªPÿÿº»| - ¦MN® > ? A B CC‚$$$$ ÿ$=$$$$$$$$$#& tÑ®ijæ áÑ®klm º&p&r9ÙHHÚ(ÿáÿâùFG(üHHÚ(d'@=à/Ð Ð@H-:LaserWriter 8 ChicagoNew YorkGenevaMonacoPalatinoTimes HelveticaCourierSymbol ºDeltaSymbol&p Espy Sans&rEspy Sans Bold9ÙeWorld Tight€€€EdWEÝmØºÊÔÖØÙÛÜÝÞßáêì$:y| - c f ¦MN® > ? A C\]klmn‚¼€Ðù€Ñ€Ñ€Ñ€Ñ€Ñ €Ñ€Ñ€Ñ €Ñ€Ñ€Ñ€Ñ€ÑS€Ñi€ Ð€Ðò KÑ¨òÑ© QÑª áÑ« ãÑ€ý€Ðö€Ð÷€Ðø2CH141 Test 1 1994Whitney KingWhitney King