Reading Ch. 25.1-25.2 H-atom
Handin homework: General Chemistry Test, : Due date 02/14/2011.
Homework to hand in: Handin 1, : Due date 02/07/2011.
Reading: Shattuck- Foundations of Quantum Mechanics Ch. 23.1-23.3
Read for Monday lab: T1 Determination of beta-ionone.
Read for Monday lab: Atkins Ch18:18.1-18.5,18.7-18.11
NMR periodic table,
Homework to hand in: Handin 2,
Spectral Deconvolution Excel Example
Spectral Deconvolution: Bromothymol Blue
: Due date 02/14/2014.
Check out the photos Erwin Schrodinger and Werner Heisenberg,
Reading: Claridge 2.1-2.5.2
Reading: Shattuck-Ch. 23.4-23.6
Homework (not to hand in): Shattuck-Ch. 23: 1,7,11,20,21,23
An applet to calculate Fourier transforms, (by Jeff Clymer)
Interactive NMR Frequency Map, (use Firefox)
Homework (not to hand in): Shattuck-Ch. 23: 26-31,33,34,37,42,45
Print off and bring to lab on Tuesday: MOE Exercises, sections: Checklist for Molecular Mechanics Calculations and Chapts 9 & 10: Dynamics in Small Peptides
Scanning tunneling microscopy: Quantum Electron Corrals
Background reading for lab on NMR: Claridge 2.1-2.5.2, 5.1-5.4
Possible terpines for the NMR experiment: terpines,
Reading: Shattuck--Ch. 23.5-23.8
Handin homework: Handin 3, : Due date 02/21/2014.
Reading: Shattuck--Ch. 23.7-23.8
Calculate the chemical shifts for beta-ionone using the GIAO, Molecular Orbital approach : Due date 02/26/2014.
Reading for Monday Lab: NOESY, Spectroscopy of beta-ionone, and Claridge: 8.1-8.3, 5.1-5.2
Homework (not to hand in): Ch 23:48-50
Reading: Harmonic Oscillator Ch 24: 1-3; Rigid Rotor Ch 24.4
Handin Homework: Handin 4, : Due date 02/28/2014.
Reading: Shattuck-Ch. 24.1-24.6,24.8 Vibration and Rotation
Homework (not to hand in) Ch. 23: 48-50 ; Ch. 24: 3,6,7,9,14,16,18,19,20,21,23
Hand in homework: Handin 5, : Due date 03/05/2014.
Home work (not to hand in): Ch. 25: 1,3,4,5 (appropriate for test coverage)
Test includes CH. 25.1 ground state of the H-atom
Note the three practice tests through the Sample Exams, link on the course home page. The following problems will not be covered on this test this year: 2004: not 3,4,10; 2012: not 1,7,and 12
Review Session: 7:00 p.m. Keyes 102
Reading Ch. 25.4-6,8,9 Multi-electron Atoms
Homework (not to hand in): Ch. 25 (Atoms):5,7,9,10,12,14,17,20,21,23,25,27,28,29,32,36
Handin Homework: Handin 6, Problem 1 only ( we did't get to Problems 2- 4 in time) : Due date 03/14/2014.
Reading for Monday"s lab: "X-ray Diffraction Studies of Powdered Crystals." in R. J. Sime, Physical Chemistry: Methods, Techniques, and Experiments
, Exp. 37. (check your e-mail).
Instrument instructions are on the lab Web page Rigaku XRD Instructions.
Also, Atkins X-ray diffraction sections: Ch 23.1-3(d). Reading due date 03/17/2014
Handin homework: Handin 6, Handin 7, For Handin 6 do just 2 and 3; for Handin 7 do just 1 and 3 : Due date 03/21/2014.
Reading Ch. 26.1-26.2 Bonding in H2
Handin due Handin due
Reading Ch. 26.3, 26.4, 26.6 (in preparation for lecture and lab)
Lab reading: MOPAC Instructions for Diatomics, Molecular Orbitals for Ozone, ( Read the Molecular Orbitals for Ozone completely. The lab report is due at the end of the lab, so you need to be ready to do the data analysis in lab).
Command script for running MOPAC on an OSX system OSX command script,
Homework (not to hand in): Ch26: 2,4,6,7,9ab,12,13,15,21,23,24,26,33(but 33 not for test 2)
Handin Homework: Handin 8, : Due date 04/04/2014.
Review/Workshop on Angular Momentum and Term Symbols (Review Ch 25.4 and 25.6 to prepare) Keyes 102 7:00 p.m.
Reading: Ch. 26.7- 26.8 Hybridization and Huckel MO
Reading for Lab on April 5: Sime, Rodney J , "Physical Chemistry: Methods, Techniques, and Experiments" Exp. 38, pp 738-741 and Exp. 40, pp 759-766 (you also might want to review Sime Exp. 37 pp. 725-733) Reading for Lab on April 7: Sime, Rodney J , "Physical Chemistry: Methods, Techniques, and Experiments" Exp. 38, pp 738-741 and Exp. 40, pp 759-766 (you also might want to review Sime Exp. 37 pp. 725-733). Reading due date 4/7/2014
Handin homework: Handin 9, (note the Monday due date) : Due date 04/14/2014.
Review session: 7:00 p.m. Keyes 102
Home work (not to hand in): Ch. 26: 27 and 28 are good preparation on hybridization for the test.
Test: (p.m.) Ch 25.2-25.6; 26.1-26.4, 26.6-26.7, 26.9
Formula sheets: Atomic Structure, Molecular Structure, will be available at the test
Vibration-Rotation Spectrum of HCl and DCl, Reading for Monday Lab
Hand in homework: Handin 10, Question 1 and IR Normal Mode Analysis of formaldehyde (skip question 2 for this week) : Due date 04/18/2014.
Reading Atkins Ch. 16.1-16.16
Homework (not to hand in): Chapt 16. Exercises: 7a,8a,11a,15a,16a,19a,20a,22a,23a,26a Problems: 5,12,15,29
Hand in homework: Handin 11, Spartan (available in Schupf lab-see signs in lab) and Gaussian (through WebMo) instructions included : Due date 04/25/2014.
Reading: Atkins: 17.1-17.4, 17.8-17.10
Homework (not to hand in): Chapt 17 Exercises: 8b,10a,16a Problems: 1,2,11,12,14,19,20,25,27
Reading: Atkins Ch. 19.1-19.5; Shattuck Ch. 12.1-12.5
Homework to hand in: Handin 12, : Due date 05/05/2014.
For lab on Tuesday: Classical Trajectory Calculations, and Atkins Ch. 27.7-27.8
Homework (not to hand in): Chapt 19. Exercises: 6a,8a,10a,11b,15a Problems: 9,14,15,16,18,22
Reading for lab on Monday: Classical trajectory calculations,
Reading Atkins Ch. 19.6-19.7, 20.1-20.2
Homework to hand in: Hand in 13, Spreadsheet with constants, (E-mail your completed spreadsheet)
Reading: Atkins 20.3
Reading: Atkins 20.3, 20.5-20.7, 27.4-27.8
Homework (not to hand in): Chapt 20. Exercises: 4a,6a,7a,12b,13a,17a Problems: 12; Chapt 27. Exercises: 13a,14a,17a Problems: 15,21
Review session 7:00 Keyes 102
Please note the two formula sheets for the material since the last test: Spectroscopy Formulas, Statistical Mechanics Formulas, (these are also available on the class notes Web page)
Homework (not to hand in): Electronic Spectroscopy Problems Answers, (problems from the in-class handout on molecular term symbols for diatomics)
The following Sections will not be covered on the Final: Atkins: 16.5d,16.7,16.8,16.16bc,16.17;17.5-17.10, Box 17.1; 18.12-18.15; 20.4,20.5, Box 20.1
Homework to hand in,
Homework to do, but not hand in.