CH342 Assignments

C^h342

02/04/2009: Wednesday

Handin homework: General Chemistry Test, : Due date 02/11/2009.

Homework to hand in: Handin 1, : Due date 02/06/2009.

02/06/2009: Friday

Read for Monday/Tuesday lab: T1 Determination of beta-ionone.

Reading McQuarrie & Simon: Chapter 1.1,1.3-1.7; (Take a look at 1.8); Math Chapter A

Homework (not to hand in): Chap. 1: 2,11,16,19,22,29; Chapt A: A2,A4,A5,A6

02/09/2009: Monday

NMR periodic table,

Homework to hand in: Handin 2, : Due date 02/13/2009.

Handin homework: Handin 3, : Due date 02/20/2009.

Hints for the handin homework: Integrals,

On-line integral tables,

02/20/2009: Friday

Reading McQuarrie and Simon: 5.1-5.7

Reading for Monday"s Lab: nOe of beta-ionone, and Claridge, Chapt. 5.1-5.4, Chapt. 8.1-8.7

Your group should sign up for an hour block of time on the NMR for Monday

Scanning Tunneling Microscopy Images: Quantum Corrals,

Homework (not to hand in): McQuarrie and Simon: Ch 4: 1(a,b,c),3,7,8,10,14(a,b),16a,20,28,30,31

02/23/2009: Monday

Reading McQuarrie and Simon Math Chapt. D

Homework to hand in: Handin 4, : Due date 02/27/2009.

02/25/2009: Wednesday

Reading: Don"t forget Wüthrich Ch. 2,6.1-6.3

Homework to hand in: Handin 5, : Due date 03/04/2009.

02/27/2009: Friday

Spherical H-atom orbitals,

Radial Probability Distribution-H atom,

Gramicidin-S grading,

Homework (not to hand in) McQuarrie and Simon: Ch. 5: 2,7,8,14,15,19,26(v=0 only),37

Homework (not to hand in): Ch: 6: 1,9,10,11,13,15,21,28,33,42

Reading: McQuarrie and Simon Ch. 6.4-6.6

03/04/2009: Wednesday

Review session: Keyes 102; 7:30 pm

03/08/2009: Sunday

Claridge 5.6-5.7. Don"t forget to read: Wüthrich 6.1-6.3, 7 (and optionally for the adventuresome Claridge 5.4-5.5)

03/09/2009: Monday

Reading: McQuarrie and Simon: 6.7, 7.1-7.4, 8.1-8.8

Gramicidin-S report due April 3 : Due date 04/03/2009.

03/13/2009: Friday

For Lab on Monday/Tuesday Rigaku Instructions, The theory is covered in Sime, "Physical Chemistry: Methods, Techniques, and Experiments" Diffraction Studies of Powdered Crystals, experiment 37 (On Reserve-electronic copy skip pp. 734-736)

03/16/2009: Monday

Homework to hand-in: Handin 7, (you"ve already done Problem 1-so you can skip Problem 1)

Reading: McQuarrie and Simon: 9.1-9.8; 11.1-11.4

Homework (not to hand in): Ch 8: 6,10,11,17,18,19,20,34,44,46

03/18/2009: Wednesday

Homework (not to hand in): Ch 7: 2,10,17,20,23,27

03/20/2009: Friday

Gramicidin-S report due April 3 04/03/2009

Homework (not to hand in): Ch. 9: 4,12,15,17,19,21,22,31,39,41

Answer to Handin 7 problem 3 (ca=-cb): Handin 7 answer,

Monday lab reading: ozone, (Note there is a pre-lab assignment and that the lab report is due at the end of the afternoon.) Reading and pre-lab due Monday March 30

03/30/2009: Monday

Handin home work: Handin 8, : Due date 04/03/2009.

Linear ozone MOPAC input file: O3-180.dat,

Here is the BF₃ MOPAC input file: BF3.dat,

The furanone MOE database file is here: furanone.mdb, or look in http://www.colby.edu/chemistry/PChem/moefiles/

Here is the script to run mopac on Colby OS-X systems: runmopac script,

For lab: MOPAC Diatomics Instructions,

Here is an updated version of the MOE tutorial exercises: MOE Tutor, (if you are having problems finding the controls for setting constraints in the new version of MOE)

04/03/2009: Friday

Handin 8 answers,

Reading for Lab on April 6/7: Sime, Rodney J , "Physical Chemistry: Methods, Techniques, and Experiments" Exp. 38, pp 738-742 and Exp. 40, pp 759-766 (you also might want to review Sime Exp. 37 pp. 725-733), which are all on electronic reserve.

Also for Monday/Tuesday Lab-- Please printout and bring: Single Crystal X-Ray Crystallography, and Crystal Structure of Potassium Permanganate, You don"t need to read these instructions before coming to lab. The corresponding theory sections in McQuarrie and Simon are 31.3-31.5

04/06/2009: Monday

Homework to hand in: Handin 9: Huckel Molecular Orbital Theory, Your molecule will be assigned on Monday morning.

Reading in McQuarrie and Simon: Ch 9.9-9.13, Ch 10(all), Ch 11.5

Reading McQuarrie and Simon: Math Chapter F Matrices

04/08/2009: Wednesday

Readng in McQuarrie and Simon: Ch. 13.1-13.5 Molecular Spectroscopy

Pulsed Fourier transfomr microwave spectroscopy: Broadband Microwave,

Homework (not to hand in): McQuarrie and Simon Ch 10: 1,2,4,7,16[see our Ozone Walsh diagram (in color) and Figure 10.25],18,27,33,35,36,41

04/10/2009: Friday

Reading: McQuarrie and Simon Ch. 13.8-9,13.13

Homework (not to handin): McQuarrie and Simon: Ch 13: 2,8,9,10,14,20,23,24,34,35,41

scissors, rock, wag, and twist, normal mode types

Test next Friday through Chapter 11 (no rotational or vibrational spectroscopy) Answers to the practice tests are on reserve in the library.

04/15/2009: Wednesday

Handin homework: Handin 10, : Due date 04/22/2009.

04/16/2009: Thursday

Review session: Thursday 7:30 Keyes 102

04/17/2009: Friday

Test: Multi-electron atoms through molecular orbitals; Chapters 7-11

04/20/2009: Monday

Homework to hand in: Handin 11, : Due date 04/27/2009.

04/22/2009: Wednesday

Handin due

04/27/2009: Monday

Homework to hand in: Handin 12, : Due date 05/01/2009.

Handin due

04/29/2009: Wednesday

Reading: McQuarrie and Simon Ch 17

05/01/2009: Friday

Handin 12 Part 2 Answers,

05/04/2009: Monday

Reading for Lab: Classical trajectory calculations on H + HF, (note the required pre-lab question imbeded in the Theory section) Read the Introduction and Theory Section for Monday/Tuesday

Homework to hand in: Handin 13, : Due date 05/08/2009.

Handin 11 answers,

Reading McQuarrie and Simon Ch. 18.1-18.8; 20.5, 20.8-20.9, 21.6