Physical Chemistry Lecture Notes

Thermodynamics, Electrochemistry, and Equilibrium

You will need the Adobe Acrobat Reader to view these files. This program is available over the InterNet or if you are on campus, from the General Server in the"Software for Use at Colby" folder. Most of the lecture notes have the same format: formula lines for the proofs but without the reasons for each step. Room is provided in the right-hand column for you to fill in with the reasons each step was taken. In this way you can concentrate on the flow of the proofs and the meaning of each formula and not worry about copying down each formula correctly for your notes.

Thermodynamics

First Law

Equipartition Theorem Predictions for Internal Energy and Cv
Van der Waals Liquifaction
Taylor Series and the Virial Equation
Non PV Work
Differential Scanning Calorimetry
Temperature Dependence of the Enthalpy of Reaction
Basic Derivatives, Isothermal Compressibility and Coefficient of Thermal Expansion
Integrating the Basic Derivatives
Cp-Cv
Joule-Thomson Expansion
Partial Derivative Conversion
First Law and Ideal Gases
Linear Curve Fitting
Error Analysis
Excel linest function
Formula Sheet 1

Entropy and Free Energy

Carnot Cycle
Ideal Gas Carnot Cycle
Thermodynamic Definition of Entropy
Ideal Gas Entropy Changes
Entropy and Phase Transitions
Termperature Dependence of the Reaction Entropy
Entropy and Spontaneous Processes
Entropy Entropy and the Surroundings for the Ideal Gas
Thermodynamic Potential Functions
Foundations of Thermodynamics
Thermodynamic Equations of State
Chemical Potential
Non-PV work and Gibbs Free Energy
The Fine Arts and Science

Phase Equilibria

Clausius-Clapeyron Equation
Ehrenfest Criteria, Second Order Phase Transitions

Solutions

Concentration Measures, Molarity, Molality, Mole Fraction
Thermodynamics of Mixing of Ideal Gases
Chemical Potentials in Solution
Boiling Point Elevation
Osmotic Pressure
Variable Pressure and Temperature Distillation
Fugacity
Visual Approach to Activity Coefficients and Henry's Law Standard States
Henry's Law constants and Free Energies of solvation
Gibb's Phase Rule
Hammett Free Energy Relationships
Isonarcotic Activity of Esters, Alcohols, Ketones, and Ethers
Formula Sheet 2

Chemical Equilibrium

Gibbs Free Energy and Chemical Equilibrium
Temperature Dependence of the Equilibrium Constant, Kp
Temperature Dependence of the Equilibrium Constant, Kp, and Entropy
Standard States and Different Concentration Measures
Molarity vs. Molality Standard States
Equilibria with Pure Liquids and Solids and the Solvent in Dilute Solution

Electrochemistry and Electrolyte Solutions

Activities of Ions in Solution
Debye-Huckel Theory
Gibbs Free Energy of Solvation and the Poisson Equation
Poisson-Boltzmann Equation
Photosynthesis Z-scheme
Ionic Activities from Electrochemical Cells
Metal Insoluble Salt Electrodes

Kinetics

1st and 2nd Order Reactions
Parallel Reactions-Competitive Reactions
Progress to Equilibrium
Consecutive Reactions Reactions
Integrating Rate Laws Using the Finite Difference Approximation
Kinetics Mechanism Simulation Introduction
First Order Rate Laws and Stella
SN1 Mechanism
Pre-Equilibrium Mechanism - Michaelis - Menten Mechanisim
Chain Mechanisms
Unimolecular Reactions- Lindemann-Henshelwood Mechanism
Dynamic NMR
Temperature Jump Kinetics
Formula Sheet 3

For more information or corrections contact Tom Shattuck at twshattu@Colby.edu.


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Last modified: 4/29/13