
1. A bonding orbital for As1O2 with 1.9614 electrons
__has 31.31% As 1 character in a sp1.64 hybrid
__has 68.69% O 2 character in a s0.69 p3 hybrid
2. A bonding orbital for As1Cl3 with 1.9539 electrons
__has 33.55% As 1 character in a s0.81 p3 d0.09 hybrid
__has 66.45% Cl 3 character in a s0.35 p3 hybrid
3. A bonding orbital for As1Cl4 with 1.9540 electrons
__has 33.56% As 1 character in a s0.82 p3 d0.09 hybrid
__has 66.44% Cl 4 character in a s0.35 p3 hybrid
4. A bonding orbital for As1Cl5 with 1.9543 electrons
__has 33.54% As 1 character in a s0.82 p3 d0.09 hybrid
__has 66.46% Cl 5 character in a s0.36 p3 hybrid
35. A lone pair orbital for O2 with 1.9690 electrons
__made from a sp0.23 hybrid
36. A lone pair orbital for O2 with 1.8575 electrons
__made from a ppi orbital ( 99.78% p 0.22% d)
37. A lone pair orbital for O2 with 1.8554 electrons
__made from a ppi orbital ( 99.78% p 0.22% d)
38. A lone pair orbital for Cl3 with 1.9893 electrons
__made from a sp0.11 hybrid
39. A lone pair orbital for Cl3 with 1.9666 electrons
__made from a p3 hybrid
40. A lone pair orbital for Cl3 with 1.9625 electrons
__made from a ppi orbital ( 99.95% p)
41. A lone pair orbital for Cl4 with 1.9893 electrons
__made from a sp0.12 hybrid
42. A lone pair orbital for Cl4 with 1.9667 electrons
__made from a p3 hybrid
43. A lone pair orbital for Cl4 with 1.9622 electrons
__made from a ppi orbital ( 99.94% p)
44. A lone pair orbital for Cl5 with 1.9893 electrons
__made from a sp0.12 hybrid
45. A lone pair orbital for Cl5 with 1.9668 electrons
__made from a p3 hybrid
46. A lone pair orbital for Cl5 with 1.9619 electrons
__made from a ppi orbital ( 99.94% p)
135. A antibonding orbital for As1Cl3 with 0.1742 electrons
__has 66.45% As 1 character in a s0.81 p3 d0.09 hybrid
__has 33.55% Cl 3 character in a s0.35 p3 hybrid
136. A antibonding orbital for As1Cl4 with 0.1738 electrons
__has 66.44% As 1 character in a s0.82 p3 d0.09 hybrid
__has 33.56% Cl 4 character in a s0.35 p3 hybrid
137. A antibonding orbital for As1Cl5 with 0.1731 electrons
__has 66.46% As 1 character in a s0.82 p3 d0.09 hybrid
__has 33.54% Cl 5 character in a s0.36 p3 hybrid
With core pairs on:A A A A A A A A A A A A A A O 2 Cl 3 Cl 3 Cl 3 Cl 3 Cl 3 Cl 4 Cl 4 Cl 4 Cl 4 Cl 4 Cl 5 Cl 5 Cl 5 Cl 5 Cl 5 
The interaction of bonding donor orbital, 1, for As1O2 with the antibonding acceptor orbital, 135, for As1Cl3 is 26.8 kJ/mol.
The interaction of bonding donor orbital, 1, for As1O2 with the antibonding acceptor orbital, 136, for As1Cl4 is 27.0 kJ/mol.
The interaction of bonding donor orbital, 1, for As1O2 with the antibonding acceptor orbital, 137, for As1Cl5 is 27.4 kJ/mol.
The interaction of bonding donor orbital, 2, for As1Cl3 with the antibonding acceptor orbital, 134, for As1O2 is 31.7 kJ/mol.
The interaction of bonding donor orbital, 2, for As1Cl3 with the antibonding acceptor orbital, 136, for As1Cl4 is 30.7 kJ/mol.
The interaction of bonding donor orbital, 2, for As1Cl3 with the antibonding acceptor orbital, 137, for As1Cl5 is 30.6 kJ/mol.
The interaction of bonding donor orbital, 3, for As1Cl4 with the antibonding acceptor orbital, 134, for As1O2 is 31.7 kJ/mol.
The interaction of bonding donor orbital, 3, for As1Cl4 with the antibonding acceptor orbital, 135, for As1Cl3 is 30.8 kJ/mol.
The interaction of bonding donor orbital, 3, for As1Cl4 with the antibonding acceptor orbital, 137, for As1Cl5 is 30.3 kJ/mol.
The interaction of bonding donor orbital, 4, for As1Cl5 with the antibonding acceptor orbital, 134, for As1O2 is 31.5 kJ/mol.
The interaction of bonding donor orbital, 4, for As1Cl5 with the antibonding acceptor orbital, 135, for As1Cl3 is 30.5 kJ/mol.
The interaction of bonding donor orbital, 4, for As1Cl5 with the antibonding acceptor orbital, 136, for As1Cl4 is 30.2 kJ/mol.
The interaction of the second lone pair donor orbital, 36, for O2 with the antibonding acceptor orbital, 136, for As1Cl4 is 61.3 kJ/mol.
The interaction of the second lone pair donor orbital, 36, for O2 with the antibonding acceptor orbital, 137, for As1Cl5 is 117. kJ/mol.
The interaction of the third lone pair donor orbital, 37, for O2 with the antibonding acceptor orbital, 135, for As1Cl3 is 116. kJ/mol.
The interaction of the third lone pair donor orbital, 37, for O2 with the antibonding acceptor orbital, 136, for As1Cl4 is 64.0 kJ/mol.
The interaction of the second lone pair donor orbital, 39, for Cl3 with the antibonding acceptor orbital, 134, for As1O2 is 26.4 kJ/mol.
The interaction of the third lone pair donor orbital, 40, for Cl3 with the antibonding acceptor orbital, 136, for As1Cl4 is 21.7 kJ/mol.
The interaction of the third lone pair donor orbital, 40, for Cl3 with the antibonding acceptor orbital, 137, for As1Cl5 is 24.0 kJ/mol.
The interaction of the second lone pair donor orbital, 42, for Cl4 with the antibonding acceptor orbital, 134, for As1O2 is 26.2 kJ/mol.
The interaction of the third lone pair donor orbital, 43, for Cl4 with the antibonding acceptor orbital, 135, for As1Cl3 is 20.6 kJ/mol.
The interaction of the third lone pair donor orbital, 43, for Cl4 with the antibonding acceptor orbital, 137, for As1Cl5 is 25.3 kJ/mol.
The interaction of the second lone pair donor orbital, 45, for Cl5 with the antibonding acceptor orbital, 134, for As1O2 is 26.2 kJ/mol.
The interaction of the third lone pair donor orbital, 46, for Cl5 with the antibonding acceptor orbital, 135, for As1Cl3 is 22.0 kJ/mol.
The interaction of the third lone pair donor orbital, 46, for Cl5 with the antibonding acceptor orbital, 136, for As1Cl4 is 24.3 kJ/mol.
The interaction of antibonding donor orbital, 135, for As1Cl3 with the antibonding acceptor orbital, 134, for As1O2 is 20.7 kJ/mol.
The interaction of antibonding donor orbital, 136, for As1Cl4 with the antibonding acceptor orbital, 134, for As1O2 is 20.2 kJ/mol.
50  0.730
49  2.257
48  2.289
47  5.297
46 ^v 8.121
45 ^v 8.132
44 ^v 8.629
43 ^v 8.951
42 ^v 8.963
41 ^v 9.289
40 ^v 9.391
39 ^v 9.402
38 ^v 11.25
37 ^v 12.04
36 ^v 12.06
35 ^v 15.99
34 ^v 21.42
33 ^v 21.43
32 ^v 22.35
31 ^v 24.94
30 ^v 46.38 29 ^v 46.39
28 ^v 46.46 27 ^v 46.46
26 ^v 46.47
25 ^v 136.9
24 ^v 137.0
23 ^v 137.0
22 ^v 188.1
21 ^v 191.5 20 ^v 191.5 19 ^v 191.5 18 ^v 191.5 17 ^v 191.5 16 ^v 191.5
15 ^v 191.8 14 ^v 191.8 13 ^v 191.9
12 ^v 249.9 11 ^v 249.9 10 ^v 249.9
9 ^v 507.6
8 ^v 1300.
7 ^v 1300.
6 ^v 1300.
5 ^v 1451.
4 ^v 2731. 3 ^v 2731. 2 ^v 2731.
1 ^v 11526
Total electronic energy = 3691.7593946321 Hartrees