You will need the Adobe Acrobat Reader to view these files. This program is available over the InterNet or if you are on campus, from the General Server in the"Software for Use at Colby" folder. Most of the lecture notes have the same format: formula lines for the proofs but without the reasons for each step. Room is provided in the right-hand column for you to fill in with the reasons each step was taken. In this way you can concentrate on the flow of the proofs and the meaning of each formula and not worry about copying down each formula correctly for your notes.

Van der Waals Liquifaction

Taylor Series and the Virial Equation

Non PV Work

Differential Scanning Calorimetry

Temperature Dependence of the Enthalpy of Reaction

Basic Derivatives, Isothermal Compressibility and Coefficient of Thermal Expansion

Integrating the Basic Derivatives

C

Joule-Thomson Expansion

Partial Derivative Conversion

First Law and Ideal Gases

Linear Curve Fitting

Error Analysis

Excel linest function

Formula Sheet 1

Ideal Gas Carnot Cycle

Thermodynamic Definition of Entropy

Ideal Gas Entropy Changes

Entropy and Phase Transitions

Termperature Dependence of the Reaction Entropy

Entropy and Spontaneous Processes

Entropy Entropy and the Surroundings for the Ideal Gas

Thermodynamic Potential Functions

Foundations of Thermodynamics

Thermodynamic Equations of State

Chemical Potential

Non-PV work and Gibbs Free Energy

The Fine Arts and Science

Ehrenfest Criteria, Second Order Phase Transitions

Thermodynamics of Mixing of Ideal Gases

Chemical Potentials in Solution

Boiling Point Elevation

Osmotic Pressure

Variable Pressure and Temperature Distillation

Fugacity

Visual Approach to Activity Coefficients and Henry's Law Standard States

Henry's Law constants and Free Energies of solvation

Gibb's Phase Rule

Hammett Free Energy Relationships

Isonarcotic Activity of Esters, Alcohols, Ketones, and Ethers

Formula Sheet 2

Temperature Dependence of the Equilibrium Constant, Kp

Temperature Dependence of the Equilibrium Constant, Kp, and Entropy

Standard States and Different Concentration Measures

Molarity vs. Molality Standard States

Equilibria with Pure Liquids and Solids and the Solvent in Dilute Solution

Debye-Huckel Theory

Gibbs Free Energy of Solvation and the Poisson Equation

Poisson-Boltzmann Equation

Photosynthesis Z-scheme

Ionic Activities from Electrochemical Cells

Metal Insoluble Salt Electrodes

Parallel Reactions-Competitive Reactions

Progress to Equilibrium

Consecutive Reactions Reactions

Integrating Rate Laws Using the Finite Difference Approximation

Kinetics Mechanism Simulation Introduction

First Order Rate Laws and Stella

SN1 Mechanism

Pre-Equilibrium Mechanism - Michaelis - Menten Mechanisim

Chain Mechanisms

Unimolecular Reactions- Lindemann-Henshelwood Mechanism

Dynamic NMR

Temperature Jump Kinetics

Formula Sheet 3

For more information or corrections contact Tom Shattuck at [email protected]

Last modified: 4/29/13